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1
Stand a little farther left or lower so the lion’s face sits against a cleaner patch of foliage rather than the densest overhead mass.
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2
Try both orientations in the field: keep vertical for the mane, but also shoot a tighter vertical head-and-mane frame and a wider horizontal that includes more body and habitat.
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3
Place the head near the upper-right third, leaving just enough space above the muzzle for the upward gaze but not so much that the canopy dominates.
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4
If grass is unavoidable, shift position by even a few inches to open a cleaner gap across the chest and lower jaw line before shooting a burst.
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5
With the 400mm at f/3.2, depth separation is attractive, but for this kind of portrait consider f/4 to f/4.5 when possible for a bit more face-to-mane consistency while still keeping the background soft.
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6
Your 1/2000 shutter speed is excellent for wildlife insurance; if the lion is calm and light is low, you could test 1/1250 to 1/1600 to reduce ISO and recover a little more shadow quality.
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7
Aim for side-lit or slightly front-side-lit conditions in early morning or late afternoon; this will add more dimensionality to the muzzle and mane than flatter overhead shade.
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8
Wait for one more expression variant: eyes just barely open, nose lifted a touch higher, or tongue/flehmen behavior to intensify the narrative.
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9
Upload a sequence from the same encounter next: one wider frame for context, one tighter face crop, and one version with cleaner foreground separation so composition choices can be compared directly.