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1
Stand 1-2 steps farther left and slightly lower so the two figures separate more cleanly against different background tones rather than merging at the overlap.
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2
Keep a horizontal orientation, but frame a little tighter on the left edge to eliminate accidental intrusions and to center attention on the crossing moment.
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3
With a 90mm lens on the D800, try f/8 to f/11 instead of f/22; at this subject distance you should still have enough depth of field for both figures while gaining noticeably better sharpness.
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4
If light allows, raise shutter speed to around 1/320 or 1/500 for walking subjects, and let ISO rise modestly if needed rather than stopping down to f/22.
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5
Wait for the exact instant when the man’s leading leg and the woman’s reaching hand are more clearly separated, or when their faces are not partially competing in profile overlap.
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6
Use the wall as a stage: place subjects in the center-right third and avoid letting bright signs sit directly above them unless the text is essential to the story.
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7
If processing in black-and-white, keep the grit but back off global grain or excessive clarity slightly; add selective contrast to faces and hands instead of everywhere.
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8
Upload next: a short sequence from the same location with 3-5 frames taken half a second apart, plus one wider establishing shot and one version made at f/8 or f/11 for comparison.